Silver Ion Catalysed Oxidation of Primary Aliphatic Amines by Potassium Peroxydisulfate — A Kinetic Study
نویسندگان
چکیده
منابع مشابه
Oxidation of Methyl Orange Solution with Potassium Peroxydisulfate
Oxidation of Methyl Orange (MO) solution in potassium peroxydisulfate (KPS) homogeneous reaction system without UV irradiation was investigated. The result shows that decolorization of MO increases as the dosage of K2S2O8 increases. The kinetic results demonstrate that the decolorization reaction is a pseudo first-order reaction when the concentration of MO ...
متن کاملQuinolinium Dichromate Oxidation of Aliphatic Aldehydes: A Kinetic Study
Kinetic data on the rates of quinolinium dichromate oxidation of a series of aliphatic aldehydes have been determined and discussed with reference to aldehyde hydration equilibria. Kinetic results support a pathway proceeding via a rate-determining oxidative decomposition of a chromate ester of an aldehyde hydrate. A cyclic transition state is suggested; being a Hückel-type system (4n + 2), thi...
متن کاملOxidation of aliphatic amines by brain and other tissues.
IN view of the finding of Quastel & Wheatley [1933, 1] that certain amines, such as isoamylamine, inhibit the respiration of brain tissue, an investigation has been made of the power of various organs to detoxicate such amines. It was found early in the work that isoamylamine is broken down by brain cortex, and this finding caused attention to be turned to the oxidation of the simpler aliphatic...
متن کاملScandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines.
A homoleptic scandium trialkyl complex in combination with a borate compound served as an excellent catalyst for the C-H addition of aliphatic tertiary amines to olefins. This highly regiospecific, 100% atom efficient C-H bond alkylation reaction was applicable to a wide variety of tertiary amines and olefins, including functionalised styrenes and unactivated α-olefins. This work represents the...
متن کاملEnhanced Oxidation of Azo Dye Using Ag-SiO2 Nanoparticle and Peroxydisulfate and Kinetic Study
Present work investigates the capability of oxidative treatment process in the presence of nano silver doped on silicate particles for decolorization of a widely used azo dye, C.I. Direct Blue 129 (DB129) in water samples. Solutions with initial concentration of 20 mgL-1 of dye, within the range of generic concentration in textile wastewaters, were treated under ambient conditions of initial pH...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1976
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.49.1820